Theoretical analyses of acidization dissolution front instability in fluid‐saturated carbonate rocks     

Chongbin Zhao  B. E. Hobbs  A. Ord 《国际地质力学数值与分析法杂志》2013,37(13):2084-2105

This paper presents an instability theory that can be used to understand the fundamental behavior of an acidization dissolution front when it propagates in fluid‐saturated carbonate rocks. The proposed theory includes two fundamental concepts, namely the intrinsic time and length of an acidization dissolution system, and a theoretical criterion that involves the comparison of the Zhao number and its critical value of the acidization dissolution system. The intrinsic time is used to determine the time scale at which the acidization dissolution front is formed, while the intrinsic length is used to determine the length scale at which the instability of the acidization dissolution front can be initiated. Under the assumption that the acidization dissolution reaction is a fast process, the critical Zhao number, which is used to assess the instability likelihood of an acidization dissolution front propagating in fluid‐saturated carbonate rocks, has been derived in a strictly mathematical manner. Based on the proposed instability theory of a propagating acidization dissolution front, it has been theoretically recognized that: (i) the increase of the mineral dissolution ratio can stabilize the acidization dissolution front in fluid‐saturated carbonate rocks; (ii) the increase of the final porosity of the carbonate rock can destabilize the acidization dissolution front, while the increase of the initial porosity can stabilize the acidization dissolution front in fluid‐saturated carbonate rocks; (iii) the increase of the mineral dissolution ratio can cause an increase in the dimensionless propagation speed of the acidization dissolution front; (iv) the increase of the initial porosity can enable the acidization dissolution front to propagate faster, while the increase of the final porosity can enable the acidization dissolution front to propagate slower in the acidization dissolution system. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

陆架边缘海沉积物有机碳矿化及其对海洋碳循环的影响     

张咏华  吴自军 《地球科学进展》2019,(2):202-209

边缘海沉积物是海洋重要的碳储库,其内部的碳循环主要是由有机质矿化分解过程来驱动的。有机碳进入边缘海沉积物后,矿化分解为溶解无机碳(DIC)进入沉积物孔隙水并扩散到上层水柱,参与海洋系统碳循环;同时还有部分DIC与钙镁等离子结合形成自生碳酸盐,保存于沉积物碳库。从生物地球化学角度探讨有机质埋藏机制和效率,在此基础上重点综述沉积物硫酸盐还原、产甲烷和甲烷厌氧氧化过程的耦合机制,以及有机质矿化对自生碳酸盐形成的影响等方面的研究进展,以期加深对陆架边缘海沉积物在全球碳循环收支平衡中的作用及其气候环境效应的认识。  相似文献   

湖泊碳酸盐在过去环境变化研究中的应用   总被引：2，自引：0，他引：2       下载免费PDF全文

郭金春  马海州  宋恩玉  陈宁 《盐湖研究》2008,16(2):66-72

国内外的研究成果表明,湖泊沉积碳酸盐矿物及其微量元素、同位素分布特征记录了全球或区域古气候环境演变历史,可以从中提取大量定量化的古气候参数。因此,可以根据湖泊碳酸盐矿物的含量和碳、氧同位素变化等信息推知其形成时期的气候环境,重建古环境,揭示气候环境演变的规律。湖泊碳酸盐是一种研究古环境演化重要的代用指标,在过去气候环境变化研究中有广阔的应用前景。  相似文献   

碳酸锂生产工艺的研究进展   总被引：6，自引：2，他引：4       下载免费PDF全文

祝增虎  朱朝梁  温现明  诸葛芹  凌宝萍 《盐湖研究》2008,16(3)

简要介绍了碳酸锂的几种不同用途。详细阐述了以锂辉石、盐湖卤水、海水为原料提取碳酸锂的几种不同的生产工艺和工艺特点,并分析了各工艺的优缺点。指出了在简化工艺、降低成本生产碳酸锂的同时要兼顾盐湖资源综合利用和环境保护是今后研究开发的方向  相似文献   

Diagenetic fluid evolution and water-rock interaction model of carbonate cements in sandstone: An example from the reservoir sandstone of the Fourth Member of the Xujiahe Formation of the Xiaoquan-Fenggu area,Sichuan Province,China   总被引：1，自引：0，他引：1  

LIU SiBing  HUANG SiJing  SHEN ZhongMin  Lü ZhengXiang  SONG RongCai 《中国科学:地球科学(英文版)》2014,57(5):1077-1092

Carbonate cement is the most abundant cement type in the Fourth Member of the Xujiahe Formation in the Xiaoquan-Fenggu area of the West Sichuan Depression. Here we use a systematic analysis of carbonate cement petrology, mineralogy, carbon and oxygen isotope ratios and enclosure homogenization temperatures to study the precipitation mechanism, pore fluid evolution, and distribution of different types of carbonate cement in reservoir sand in the study area. Crystalline calcite has relatively heavy carbon and oxygen isotope ratios(δ13C = 2.14‰, δ18O = -5.77‰), and was precipitated early. It was precipitated directly from supersaturated alkaline fluid under normal temperature and pressure conditions. At the time of precipitation, the fluid oxygen isotope ratio was very light, mainly showing the characteristics of a mixed meteoric water-seawater fluid(δ18O = -3‰), which shows that the fluid during precipitation was influenced by both meteoric water and seawater. The calcite cement that fills in the secondary pores has relatively lighter carbon and oxygen isotope ratios(δ13C = -2.36‰, δ18O = -15.68‰). This cement was precipitated late, mainly during the Middle and Late Jurassic. An important material source for this carbonate cement was the feldspar corrosion process that involved organic matter. The Ca2+, Fe3+ and Mg2+ ions released by the clay mineral transformation process were also important source materials. Because of water-rock interactions during the burial process, the oxygen isotope ratio of the fluid significantly increased during precipitation, by about 3‰. The dolomite cements in calcarenaceous sandstone that was precipitated during the Middle Jurassic have heavier carbon and oxygen isotope ratios, which are similar to those of carbonate debris in the sandstone(δ13C = 1.93‰, δ18O = -6.11‰), demonstrating that the two are from the same source that had a heavier oxygen isotope ratio(δ18O of about 2.2‰). The differences in fluid oxygen isotope ratios during cement precipitation reflect the influences of different water-rock interaction systems or different water-rock interaction strengths. This is the main reason why the sandstone containing many rigid particles(lithic quartz sandstone) has a relatively negative carbon isotope ratio and why the precipitation fluid in calcarenaceous sandstone has a relatively heavier oxygen isotope ratio.  相似文献   

测井曲线旋回分析在碳酸盐岩层序地层研究中的应用^*   总被引：4，自引：2，他引：2  

伊海生 《古地理学报》2011,13(4):456-466

在碳酸盐岩台地沉积层序的研究中,通过旋回计数和厚度测量,采用费希尔图解法解析高频米级旋回或副层序的叠置形式和空间结构,进而标定三级沉积层序的界面,是目前普遍采用的一个方法。但是,这一方法目前主要用于露头层序地层学研究,而在地下油气勘探区受到极大的限制。文中提出了一种新的计算方法,它可以根据测井资料求取任一地层段沉积旋回的个数和厚度。根据数值模拟,详细讨论了海平面变化周期和幅度与沉降速率、沉积速率的相关关系,提出高频沉积旋回的分布模式和叠加样式可以指示低频海平面变化的轨迹,这为划分三级沉积层序、标定层序界面提供了理论依据。最后,以川西北地区中三叠统雷口坡组为例,说明了应用自然伽马测井资料进行数据处理的流程和步骤,以及根据旋回厚度累积偏差曲线标定层序界面的位置、识别旋回谱系标志。  相似文献   

塔里木盆地巴麦地区石炭系低速异常碳酸盐岩的解释     

郭倩  蒲仁海 《吉林大学学报(地球科学版)》2011,41(3):689-696

巴麦地区即塔西南巴楚隆起-麦盖提斜坡,具有台地边缘-斜坡的古构造和古地理背景,这种台地边缘和典型的浅滩沉积暗示了该区具有发育生物礁的环境特征。区内先巴扎（XBZ）600 km²三维地震探区石炭系发育了巴楚组（C₁b）生屑灰岩及标准灰岩、小海子组（C₂x）3套灰岩,其中小海子组发现特殊响应碳酸盐岩,主要表现为厚度增大、频率增高、多出一条波峰同相轴的地震响应特征。通过差异厚度法、底面拉平法、地震属性法、正反演模型法,结合野外露头、岩心、镜下观察、录井、沉积相等综合分析,可初步推测该低速异常体为厚度增加、孔隙度增大的近东西向台地边缘障壁礁所致。礁体东西走向延伸超过25 km,礁核区小海子组灰岩最厚62 m,礁外的小海子组50 m。台缘斜坡南倾,坡度陡,水平宽度1~2 km。礁后生屑滩北倾,坡度缓,水平宽度3~6 km。受色力布亚断裂带遮挡,该生物礁储层可以形成有利圈闭,面积约为42 km²,厚约45 m。  相似文献   

异地碳酸盐岩块体与碳酸盐岩重力流沉积研究及展望   总被引：3，自引：0，他引：3       下载免费PDF全文

牛新生  王成善 《古地理学报》2010,12(1):17-30

异地碳酸盐岩块体是指已固结或半固结的、经过一定距离搬运再沉积而产于正常沉积地层中规模 较大的碳酸盐岩块,它和碳酸盐岩重力流沉积均属于再沉积碳酸盐岩。文章分析了岩崩、岩屑崩坍、海底滑坡、 滑塌和碎屑流沉积的过程,讨论了异地碳酸盐岩块体的沉积机制;归纳了异地碳酸盐岩块体形成的主要地质背 景,认为异地碳酸盐岩块体可见于活动大陆边缘、被动大陆边缘、海山和前陆盆地等地质环境中;着重介绍了 异地碳酸盐岩块体和碳酸盐岩重力流沉积的研究进展,即线源式的碳酸盐岩裙沉积和点源式的碳酸盐岩海底扇 沉积;最后,阐释了滑来岩块、滑塌堆积和碎屑流沉积的区别与联系,总结了孤立碳酸盐岩块体的搬运沉积机 制,对比区分了碳酸盐岩裙沉积和碳酸盐岩海底扇的沉积特征,认为它们在斜坡环境、沉积物类型和沉积特征 等方面存在诸多不同。  相似文献   

湖泊自生碳酸盐碳同位素在环境变化中的应用   总被引：1，自引：0，他引：1       下载免费PDF全文

曾承 《盐湖研究》2010,18(2)

湖泊自生碳酸盐碳同位素组成(δ13Cc)在区域气候与环境变化方面的应用研究近年来进展迅速,成果显著,保存在各类湖泊沉积物柱芯中的δ13Cc记录揭示了湖表水体与大气CO2的交换程度、暖季降水量的多少、流域C3和C4植被变化情况、水生生物光合作用或呼吸作用强弱、湖泊生产力大小、湖泊水体化学特征、湖水不同深度层的有机质变化过程等重要的气候和环境信息;对此进行归纳和述评。  相似文献   

湖泊自生碳酸盐氧同位素环境记录研究：（一）环境解释模型          下载免费PDF全文

曾承  王臣旗 《盐湖研究》2009,17(2):1-4

湖泊自生碳酸盐氧同位素组成(δ18OC)在区域气候与环境变化方面的应用研究近年来发展迅速,成果令人瞩目,保存在各类湖泊沉积物柱芯中的δ18OC记录揭示了湖泊水温乃至汇水区域气温,湖泊不同水深处的水温差异、湖泊水位、降水δ18O、冰川融水δ18O、湖水盐度等重要的气候和环境信息。对前人通过研究来自不同类型湖泊、具不同曲线形态的δ18OC记录提出的多种环境解释模型进行了归纳。  相似文献